UEFA Champions League finalen 2010

UEFA Champions League finalen 2010 var en fodboldkamp der blev spillet den 22. maj 2010. Kampen blev spillet på Santiago Bernabéu i Madrid, og skulle finde vinderen af UEFA Champions League 2009-10. De deltagende hold var tyske Bayern München og italienske Inter Milano metal water jug. Kampen blev vundet af Inter med 2-0, der sikrede sig The Treble for første gang i klubbens historie, og første gang for en italiensk klub. Forinden havde klubben i samme sæson vundet Serie A og Coppa Italia.

Det var Inters tredje sejr i turneringen, og deres første siden 1965, ligesom det var deres første finale i den største europæiske holdturneringen siden 1972, hvor de tabte til Ajax Amsterdam. Bayern München havde seneste vundet UEFA Champions League i 2001 hvor de besejrede Valencia. Dette var også første gang siden 2002 at der var tysk deltagelse i finalen, da Bayer Leverkusen tabte til Real Madrid. Finalen var også den første hvor der ikke var et engelsk hold som deltager, siden 2004 hvor AS Monaco tabte til FC Porto. Santiago Bernabéu havde tre gange tidligere lagt græs til en Champions League-finale, da der også blev spillet i Madrid i 1957, 1969 og 1980 bpa free plastic water bottles. Det var den første finale i turneringens historie der blev spillet på en lørdag, da alle foregående var afholdt om onsdagen.

Kampen blev ledet af den engelske dommer Howard Webb.

Foran 73.170 tilskuere tog Inter føringen i det 35. minut, da argentineren Diego Milito scorede kampens første mål case waterproof. Efter 70 minutter øgede Milito til 2-0, som også blev kampens resultat running belt india.

Inter-spillerne Milito blev af UEFA kåret til kampens bedste spiller, og Wesley Sneijder blev af fansene kåret til den bedste. Inters træner José Mourinho meddelte efter kampen at han forlod klubben, da han ville prøve at vinde Champions League med tre forskellige klubber. Han havde i 2004 vundet trofæet med FC Porto.

UEFA Kampens bedste spiller:
Diego Milito (Inter)
Fans’ Kampens bedste spiller:
Wesley Sneijder (Inter)

Linjedommere:
Mike Mullarkey (England)
Darren Cann (England)
Fjerde dommer:
Martin Atkinson (England)
Reserve dommer:
Peter Kirkup (England)


Hospital Corporation of America

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Hospital Corporation of America, ou HCA est le plus grand groupe hospitalier privé au monde. Basé à Nashville, dans le Tennessee running bottle holder, il est considéré comme le principal facteur qui fait de cette ville un point névralgique en matière de soins de santé. Le groupe gère 273 établissements de soins intensifs, centres chirurgicaux, hôpitaux psychiatriques et maisons de convalescence dans une vingtaine d’États. Il possède également des cliniques en Suisse et en Grande-Bretagne

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HCA est fondé en 1968 par des membres de la famille Frist, Thomas Frist et son fils Thomas Jr Frist. L’actuel chef de la majorité républicaine au sénat américain et fils de Thomas Frist, Bill Frist, possède des parts dans la compagnie. La majeure partie de sa fortune running belt india, estimée à plus ou moins 20 millions de dollars, est le fruit de sa participation dans le HCA. Jack O. Bovender, Jr., est quant à lui directeur général de HCA. Il est un diplômé de l’université Duke.

HCA a réalisé en 2005 un chiffre d’affaires de 24,5 milliards de dollars et un bénéfice de 1,4 milliard.

En octobre 2014, HCA annonce l’acquisition de CareNow, une entreprise de services d’urgence au Texas pour environ 1 milliard de dollars.

Tetramethylurea

Tetramethylurea is a aprotic-polar solvent for organic compounds, especially for aromatic compounds and is used e. g. for Grignard reagents.

The acute toxicity of tetramethylurea is moderate. However, it turned out to be embryotoxic and teratogenic towards several animal species and should therefore be used under appropriate safety precautions.

The synthesis and properties of tetramethylurea were comprehensively described by Arthur Lüttringhaus 1963. The synthesis variant preferred by the authors is based on diphenyl carbonate (used for the preparation of polycarbonates) which is reacted with gaseous dimethylamine in an autoclave providing a yield of 74 %.

Tetramethylurea is formed in the reaction of dimethylcarbamoyl chloride with anhydrous sodium carbonate in a yield of 96.5% vacuum meat tenderizer.

Dimethylcarbamoyl chloride also reacts with excess dimethylamine forming tetramethylurea. Even though the product is contaminated and smelly it may be purified by addition of calcium oxide and subsequent fractional distillation.

The reaction of dimethylamine with phosgene in the presence of e. g. 50 % sodium hydroxide solution and subsequent extraction with 1,2-dichloroethane yields tetramethylurea in 95% yield.

The reactions with dimethylcarbamoyl chloride or phosgene are highly exothermic and the removal of the resulting dimethylamine hydrochloride requires some effort.

Tetramethylurea is also formed during the oxidation of tetrakis(dimethylamino)ethylene (TDAE), a very electron-rich alkene and a strong reducing agent, available from tris (dimethylamino) methane by pyrolysis or from chlorotrifluoroethene and dimethylamine.

TDAE reacts with oxygen in a (2+2) cycloaddition reaction to a 1,2-dioxetane which decomposes to electronically excited tetramethylurea. This returns to the ground state while emitting green light with an emission maximum at 515 nm.

Tetramethylurea is a clear, colorless liquid with mild aromatic odor that is miscible with water and many organic solvents. Unusual for an urea is the liquid state of tetramethylurea in a range of &gt where to buy reusable water bottles; 170 °C.

Tetramethylurea is miscible with a variety of organic compounds, including acids such as acetic acid or bases such as pyridine and an excellent solvent for organic substances such as ε-caprolactam or benzoic acid and dissolves even some inorganic salts such as silver nitrate or sodium iodide. Due to its distinct solvent properties tetramethylurea is often used as a replacement for the carcinogenic hexamethylphosphoramide (HMPT).

Tetramethylurea is suitable as a reaction medium for the polymerization of aromatic diacid chlorides (such as isophthalic acid) and aromatic diamines (such as 1,3-diaminobenzene(m-phenylenediamine)) to aramids such as poly (m-phenylene isophthalamide) (Nomex®)

The polymerization of 4-amino benzoic acid chloride hydrochloride in tetramethylurea provides isotropic viscous solutions of poly(p-benzamide) (PPB) pill shaver, which can be directly spun into fibers.

In a tetramethylurea-LiCl mixture stable isotropic solutions can be obtained up to a PPB polymer concentration of 14%.

Tetramethylurea also dissolves cellulose ester and swells other polymers such as polycarbonates, polyvinyl chloride or aliphatic polyamides, usually at elevated temperature.

Strong and hindered non-nucleophilic guanidine bases are accessible from tetramethylurea in a simple manner, which are in contrast to the fused amidine bases DBN or DBU not alkylated.

A modification of the Koenigs-Knorr reaction for building glycosides from 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide (acetobromoglucose) originates from S. Hanessian who used the silver salt silver trifluoromethanesulfonate (TfOAg) and as a proton acceptor tetramethylurea. This process variant is characterized by a simplified process control, high anomeric purity and high yields of the products. If the reaction is carried out with acetobromoglucose and silver triflate/tetramethylurea at room temperature, then tetramethylurea reacts not only as a base running belt india, but also with the glycosyl to form a good isolable uroniumtriflats in 56% yield.